• Flower-shaped ZnO–CeO$_2$ nanorectangulates: an efficient photocatalyst for degradation of endocrine disruptor 2,4-dichlorophenoxy acetic acid under visible light

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      https://www.ias.ac.in/article/fulltext/boms/045/0106

    • Keywords

       

      Photocatalysis; endocrine disruptor; visible light; nanocomposite; ZnO; CeO$_2$.

    • Abstract

       

      Nanosized, rectangularly arranged ZnO–CeO$_2$ nanoflowers were prepared by a simple hydrothermal technique. The prepared nanocomposites were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), UV–visible differential reflectance spectroscopy, field-emission scanning electron microscope, X-ray photoelectron spectroscopy, electron paramagnetic resonance and Brunauer-Emmett-Teller techniques. Different compositions of composites were prepared and the best composition was used for conducting the photocatalytic studies. The degradation of 2,4-dichlorophenoxy acetic acid (2,4-D), a herbicide and endocrine-disrupting agent, was performed under visible-light irradiation. The results showed the nanocomposite to be in a flower-like structure comprising of rectangular-shaped ZnO on which CeO$_2$ particles were evenly distributed. This flower-shaped ZnO–CeO$_2$ nanorectangulate composite comprises particle sizes ranging from 50–100 nm of rectangular thickness and 10–20 nm spherical particles. The XRD and FT-IR results prove the presence of ZnO and CeO$_2$ in the prepared nanocomposite. The bandgap energy was found to be 3.18 eV. X-ray photoelectron spectroscopy proved the presence of Ce as Ce$^{4+}$ (CeO$_2$) in the prepared composite. A comparative study of nanocomposite and pristine ZnO showed increased activity. The photocatalytic preliminary and kinetic studies were conducted. The reaction followed pseudo-first-order kinetics. The UV–visible absorption spectrum and chemical oxygen demand decrease proved the complete degradation of the endocrine disruptor 2,4-D under visible-light irradiation.

    • Author Affiliations

       

      G A SUGANYA JOSEPHINE1 K JAYAPRAKASH2 A SIVASAMY2

      1. Department of Chemistry, Aarupadai Veedu Institute of Technology – Vinayaka Mission Research Foundation, Rajiv Gandhi Salai, Chennai 603104, India
      2. Chemical Engineering Area, CSIR-Central Leather Research Institute, Chennai 600020, India
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