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      https://www.ias.ac.in/article/fulltext/boms/045/0043

    • Keywords

       

      Dy$^{3+}$:fluorophosphate glasses; DTA; bandgap energies; photoluminescence decay; photometric parameters.

    • Abstract

       

      Fluorophosphate (PAKCLf: P$_2$O$_5$–Al$_2$O$_3$–K$_2$O–CaF$_2$–LiF) glasses with Dy$^{3+}$ concentration of 0.01, 0.05, 0.1, 0.5, 1.0, 2.0 and 3.0 mol% were fabricated by pouring the melt and sudden quenching process. The glass stability factor of 106°C was calculated by glass transition (563°C) and crystallite (669°C) temperatures. The energy bandgap (E$_g$) of Dy$^{3+}$:PAKCLf glasses is calculated for (${\alpha}$hm)$^2$ (direct) and (${\alpha}$hm)$^{1/2}$ (indirect) allowed transitions. From optical absorption, the oscillator strength and spectroscopic intensity (${\Omega}_{2,4,6}$) parameters by performing Judd–Ofelt calculations were estimated to evaluate the radiative transition properties of ${}^4$F$_{9/2}$ level in Dy$^{3+}$ ions. The emission spectra consist of two intense bands in blue (485 nm: ${}^4$F$_{9/2}$${\rightarrow}$${}^6$H$_{15/2}$) and yellow (576 nm: ${}^4$F$_{9/2}$${\rightarrow}$${}^6$H$_{13/2}$) regions by stimulating at 349 nm. The decay curves demonstrate the non-exponential nature from 0.5 to 3.0 mol% of Dy$^{3+}$ and fitted well to the Inokuti–Hirayama model. The findings of stimulated emission cross-section (5.20 ${\times}$ 10$^{–21}$ cm$^2$), optical gain (29.59 ${\times}$ 10$^{–25}$ cm$^2$s), and quantum efficiency (97%) for Dy$^{3+}$:PAKCLf glasses could be potentially utilized as optical devices. The photometric parameters like CIE colour coordinates and correlated colour temperatures (CCT:6300-6900 K) of Dy$^{3+}$:PAKCLf glasses reveal the application of white light-emitting diodes.

    • Author Affiliations

       

      K KIRAN KUMAR1 RAMACHARI DODDOJI2 3 V B SREEDHAR4 NGUYEN THI QUYNH LIEN5 HO VAN TUYEN2 3 VASUDEVA REDDY MINNAM REDDY6

      1. Department of Physics, Annamacharya Institute of Technology and Sciences, Tirupati 517520, India
      2. Institute of Research and Development, Duy Tan University, Da Nang 550000, Vietnam
      3. Faculty of Natural Sciences, Duy Tan University, Da Nang 550000, Vietnam
      4. Department of Physics, R.G.M. College of Engineering and Technology, Nandyal 518501, India
      5. Faculty of Basic Sciences, Van Lang University, Ho Chi Minh City, Vietnam
      6. School of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Republic of Korea
    • Dates

       
  • Bulletin of Materials Science | News

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