• Structural, vibrational and microwave properties of $x$La(Mg$_{1/2}$Ti$_{1/2}$)O$_3$–($1 - x$)Ba(Mg$_{1/3}$Nb$_{2/3}$)O$_3$

• # Fulltext

https://www.ias.ac.in/article/fulltext/boms/044/0036

• # Keywords

Rietveld refinement; microwave dielectric; Raman spectroscopy.

• # Abstract

Vibrational and microwave dielectric properties of $x$La(Mg$_{1/2}$Ti$_{1/2}$)O$_3$–($1 - x$)Ba(Mg$_{1/3}$Nb$_{2/3}$)O$_3$ ($x = 0.0, 0.1,0.3, 0.5, 0.7, 0.9$ and 1.0) synthesized by the solid-state reaction technique are investigated. The Rietveld refinement of the X-ray diffraction (XRD) data confirms that Ba(Mg$_{1/3}$Nb$_{2/3}$)O$_3$ ($x = 0.0$) adopts the 1:2-ordered structure with trigonal P-3$m$1 space group, whereas La(Mg$_{1/2}$Ti$_{1/2}$)O$_3$ ($x = 1$) has monoclinic $P2_1/n$ crystal structure. Both the materials have single phase crystal structure. For $x = 0.1$, the sample is found to have double phase. Further, with the increase in the value of $x$, the crystal structure becomes monoclinic $P2_1/n$. The vibrational properties of the materials are studied by the Raman spectroscopy and are correlated with the structural parameters. All the materials show high dielectric constant ($\epsilon_r$ > 35) at microwave range. The factors affecting the microwave dielectric properties are discussed based on the vibrational andstructural data.

• # Author Affiliations

1. Department of Physics, Bose Institute, 93/1 Acharya Prafulla Chandra Road, Kolkata 700 009, India

• # Bulletin of Materials Science

Volume 45, 2022
All articles
Continuous Article Publishing mode

• # Dr Shanti Swarup Bhatnagar for Science and Technology

Posted on October 12, 2020

Prof. Subi Jacob George — Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bengaluru
Chemical Sciences 2020