• Synergistic effect of manganese and nitrogen codoping on photocatalytic properties of titania nanoparticles

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      https://www.ias.ac.in/article/fulltext/boms/043/0085

    • Keywords

       

      Titania nanoparticle; sol–gel; nitrogen; manganese; codoping; photocatalytic.

    • Abstract

       

      Titanium dioxide is an n-type semiconductor widely used in applications like catalysts, optoelectonic materials, ceramics, H$_2$ generation, self-cleaning, water purification and solar cells. Sol–gel method has been chosen for nanoparticle synthesis because of its easy stoichiometry control, cost effectiveness and low temperature synthesis. In this study, titanium dioxide nanoparticles doped with different amounts of manganese (Mn) and nitrogen (N) were synthesized with sol–gel method. Crystal structure of undoped, Mn-doped, and Mn–N-codoped nanoparticles were determined with X-ray diffraction (XRD) analysis. Fourier transform infrared spectroscopy (FTIR) analysis was performed to identify the functional groups of nanoparticles. Photocatalytic analysis was carried out by methylene blue degredation under UV light for 1 h. X-rayphotoelectron spectroscopy (XPS) analysis was conducted to identify the chemical state and composition of the nanoparticles. Compared to the undoped TiO$_2$, which had 79.37% efficiency, Mn-doped and Mn–N-codoped TiO$_2$ nanoparticles have shown greater photocatalytic efficiency with 86.25 and 99.11% efficiencies, respectively. The results confirm that doping ofmanganese and nitrogen has affirmative effect on photocatalytic properties of synthesized nanoparticles.

    • Author Affiliations

       

      I BIRLIK1 D DAGDELEN2

      1. Department of Metallurgical and Materials Engineering, Dokuz Eylul University, Buca, 35390 Izmir, Turkey
      2. Department of Nanoscience and Nanoengineering, The Graduate School of Natural and Applied Sciences, Dokuz Eylul University, Buca, 35390 Izmir, Turkey
    • Dates

       
  • Bulletin of Materials Science | News

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