• X-ray structure, hydrogen bonding and lattice energy analysis of (2$E$)-1-(anthracen-9-yl)-3-(4-substitutedphenyl)prop-2-en-1-ones

• # Fulltext

https://www.ias.ac.in/article/fulltext/boms/039/07/1851-1860

• # Keywords

Anthracene; prop-2-en-1-one; crystal structure; intermolecular interactions; lattice energy; PIXEL.

• # Abstract

(2$E$)-1-(anthracen-9-yl)-3-(4-chlorophenyl)prop-2-en-1-ones and (2$E$)-1-(anthracen-9-yl)-3-(4-nitrophenyl) prop-2-en-1-ones crystallize in the monoclinic crystal system with space group P2$_1$/c. Single-crystal X-ray diffraction data for both the compounds were collected on an X’Calibur CCD area detector diffractometer (Oxford Diffraction)using Mo$K\alpha$ radiation ($\lambda = 0.7107$ $\AA$) at 293(2) K. The crystal structures were solved by direct methods and refined by full-matrix least-square procedures to a final $R$ value of 0.0468 [I] and 0.0486 [II]. The crystal structures as elucidated by X-ray diffraction methods show the presence of a few intermolecular interactions, and the nature and energetics associated with these interactions have been characterized using PIXEL software.

• # Author Affiliations

1. Department of Studies in Chemistry, Mangalore University, Mangalagangothri 574 199, India
2. Department of Studies in Chemistry—Industrial Chemistry Division, Mangalore University, Mangalagangothri 574 199, India
3. X-ray Crystallography Laboratory, Post-Graduate Department of Physics and Electronics, University of Jammu, Jammu Tawi 180 006, India

• # Bulletin of Materials Science

Volume 43, 2020
All articles
Continuous Article Publishing mode

• # Editorial Note on Continuous Article Publication

Posted on July 25, 2019