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      https://www.ias.ac.in/article/fulltext/boms/039/07/1725-1733

    • Keywords

       

      Aza-Michael addition polymer; synthesis; characterisation; SEM; degradation kinetics; $E_a$.

    • Abstract

       

      Synthesis of a novel co-polymer made by the addition polymerisation between MEGDMA and 4-AB by aza-Michael addition (AMA) polymerisation method is a fascinating field of research. The present investigationyielded a hazardous metal catalyst-free and toxic solvent-free methodology. The AMA polymerisation was carried out at five different [$M_1/M_2$] values under N$_2$ atmosphere at 100$^{\circ}$C for 2 h. Thus, obtained co-polymer was characterized by Fourier transform infrared spectroscopy, UV–visible reflectance spectroscopy, X-ray diffraction, differential scanning calorimetry, thermogravimetric analysis and scanning electron microscopy (SEM). The SEM image confirmed the formation of polymer nanoparticles. The non-isothermal degradation kinetics was followed with four different models, such as Flynn-Wall-Ozawa, Auggis-Bennet, Kissinger and Friedman method. Among the modelsused, the Kissinger method yielded the lowest degradation kinetics. The degradation kinetics of the co-polymer was followed with the help of model-free methods. Moreover, it was critically compared with the literature.

    • Author Affiliations

       

      A JANCIRANI1 V KOHILA2 B MEENARATHI3 A YELILARASI4 R ANBARASAN3

      1. Department of Chemistry, Sethu Institute of Technology, Kariapatti 626 115, India
      2. Department of Chemistry, Kamaraj College of Engineering and Technology, Virudhunagar 626 001, India
      3. Department of Polymer Technology, Kamaraj College of Engineering and Technology, Virudhunagar 626 001, India
      4. Department of Physics, Kamaraj College of Engineering and Technology, Virudhunagar 626 001, India
    • Dates

       
  • Bulletin of Materials Science | News

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