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      https://www.ias.ac.in/article/fulltext/boms/038/06/1651-1663

    • Keywords

       

      Chemical synthesis; catalytic properties; solid state.

    • Abstract

       

      Five new MgAl2Si2O8 : M0.01 (M = Ni2+, Cu2+, Pd2+, Pt2+ and Ru3+) materials were developed for the reduction of nitroarenes as catalysts by conventional solid state reaction at 1300°C. The prepared materials were characterized by thermal analysis, Fourier transform infrared spectroscopy, X-ray powder diffraction analysis, scanning electron microscopy, energy-dispersive X-ray analysis and nitrogen adsorption–desorption analysis. The catalytic activities of the prepared catalysts were tested in the reduction of 2- or 4-nitroanilines in aqueous media at ambient temperature in the presence of NaBH4 by UV–vis spectrophotometer. Furthermore, the MgAl2Si2O8 : M0.01 catalysts can be recovered by filtration and reused for five cycles for the reduction of 2-nitroaniline. These results show that the MgAl2Si2O8 : M0.01 catalysts can be used in practical applications in the reduction of nitroanilines.

    • Author Affiliations

       

      Serkan Dayan1 Sevgi Öztürk1 Nilgün Kayaci1 Nilgun Kalaycioglu Ozpozan1 Esra Öztürk2

      1. Department of Chemistry, Faculty of Science, Erciyes University, Kayseri 38039, Turkey
      2. Karamanoglu Mehmetbey University, Faculty of Engineering, Department of Materials Science and Engineering, TR-70200 Karaman, Turkey
    • Dates

       
  • Bulletin of Materials Science | News

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