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      https://www.ias.ac.in/article/fulltext/boms/034/02/0251-0259

    • Keywords

       

      Nanoparticles; dielectric permittivity; interfacial polarization; activation energy.

    • Abstract

       

      Zinc aluminate nanoparticles with average particle size of 40 nm were synthesized using a sol–gel combustion method. X-ray diffractometry result was analysed by Rietveld refinement method to establish the phase purity of the material. Different stages of phase formation of the material during the synthesis were investigated using differential scanning calorimetry and differential thermogravimetric analysis. Particle size was determined with transmission electron microscopy and the optical bandgap of the nanoparticles was determined by absorption spectroscopy in the ultraviolet-visible range. Dielectric permittivity and a.c. conductivity of the material were measured for frequencies from 100 kHz to 8 MHz in the temperature range of 30–120°C. The presence of Maxwell–Wagner type interfacial polarization was found to exist in the material and hopping of electron by means of quantum mechanical tunneling is attributed as the reason for the observed a.c. conductivity.

    • Author Affiliations

       

      E Muhammad Abdul Jamal1 D Sakthi Kumar2 M R Anantharaman1

      1. Department of Physics, Cochin University of Science and Technology, Cochin 682 022, India
      2. Bio Nano Electronics Research Centre, Toyo University, Tokyo, Japan
    • Dates

       
  • Bulletin of Materials Science | News

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