• Synthesis of crosslinked poly(styrene-𝑐𝑜-divinylbenzene-𝑐𝑜-sulfopropyl methacrylate) nanoparticles by emulsion polymerization: Tuning the particle size and surface charge density

    • Fulltext


        Click here to view fulltext PDF

      Permanent link:

    • Keywords


      Colloidal particle; emulsion polymerization; polystyrene; critical micelle concentration (CMC); surface charge density; charges per particle.

    • Abstract


      We have synthesized highly charged, crosslinked poly (styrene-𝑐𝑜-divinylbenzene-𝑐𝑜-sulfopropyl methacrylate) copolymer colloidal particles using emulsion polymerization. The effects of concentration of the emulsifier and the initiator on the particle size and the charge density of the colloidal particles are studied. Colloidal particle size is highly dependent upon the concentration of the emulsifier and the initiator. The colloidal particle diameter decreases with increasing concentration of the emulsifier and increases with increasing concentration of the initiator in the polymerization mixture. Number of particles, surface charge density and charges per particle are also functions of both the emulsifier and the initiator concentration. The surface charge density and the number of charges per sphere increase with increasing particle diameter. These copolymer colloid particles self assemble readily and diffract visible light. Polymer hydrogel imbibed with these colloids shows the light diffraction.

    • Author Affiliations


      Dhamodaran Arunbabu1 Mousumi Hazarika1 Somsankar Naik1 Tushar Jana1

      1. School of Chemistry, University of Hyderabad, Hyderabad 500 046, India
    • Dates

  • Bulletin of Materials Science | News

    • Dr Shanti Swarup Bhatnagar for Science and Technology

      Posted on October 12, 2020

      Prof. Subi Jacob George — Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bengaluru
      Chemical Sciences 2020

      Prof. Surajit Dhara — School of Physics, University of Hyderabad, Hyderabad
      Physical Sciences 2020

    • Editorial Note on Continuous Article Publication

      Posted on July 25, 2019

      Click here for Editorial Note on CAP Mode

© 2022-2023 Indian Academy of Sciences, Bengaluru.