Photoluminescence and thermoluminescence properties of tricalcium phosphate phosphors doped with dysprosium and europium
K Madhukumar H K Varma Manoj Komath T S Elias V Padmanabhan C M K Nair
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The suitability of calcium phosphate crystals for thermoluminescence dosimetry (TLD) applications is investigated, owing to their equivalence to bone mineral. The 𝛼 and 𝛽 phases of tricalcium phosphate (TCP) were synthesized through wet precipitation and high temperature solid state routes and doped with Dy and Eu. The photoluminescence and thermoluminescence studies of the phosphors have been carried out.
The TL properties were found to be highly dependent on the method of preparation of the material. Eu doping gave good PL emission, whereas Dy doping was more efficient in TL emission. 𝛽-TCP was found to be less TL sensitive than 𝛼-TCP, yet it was identified as a better phosphor material owing to its better fading characteristics.
The dependence of TL of 𝛽-TCP : Dy on the energy and dose of radiation, and on the doping concentration were studied. The TL intensity was observed to fade exponentially during a storage period of 20 days, but it stabilized at 70% of the initial value after 30 days. The optimum doping concentration was found to be 0.5 mol%.
K Madhukumar1 H K Varma2 Manoj Komath2 T S Elias3 V Padmanabhan3 C M K Nair1
Volume 46, 2023
Continuous Article Publishing mode
Prof. Subi Jacob George — Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bengaluru
Chemical Sciences 2020
Prof. Surajit Dhara — School of Physics, University of Hyderabad, Hyderabad
Physical Sciences 2020
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