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    • Keywords


      Microwave materials; ceramic dielectric resonators; polytitanates; co-precipitation.

    • Abstract


      The present study focuses on critical factors limiting single-phase formation of Ba2Ti9O20 (2 : 9). Apart from 2 : 9, other polytitanates that are richer in Ti or Ba could also be prepared as single-phase material without any stabilizing agent through chemical co-precipitation. 2 : 9 is found to be a stoichiometric compound and even 0.5% excess Ti or Ba leads to multiphase formation. Single-phase 2 : 9 could be achieved even through solid-state route without the addition of stabilizing agents using high purity raw materials. The present results do not agree with existing hypotheses viz. diffusion, high surface and nucleation energy, potential barrier, non-stoichiometry etc as critical factors limiting formation of 2 : 9 as single-phase material.

    • Author Affiliations


      Unnikrishnan Gopinath1 Dhanya Chandran1 Seema Ansari1 Bindu Krishnan1 Rani Panicker1 Raghu Natarajan1

      1. Centre for Materials for Electronics Technology, Thrissur 680 771, India
    • Dates

  • Bulletin of Materials Science | News

    • Dr Shanti Swarup Bhatnagar for Science and Technology

      Posted on October 12, 2020

      Prof. Subi Jacob George — Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bengaluru
      Chemical Sciences 2020

      Prof. Surajit Dhara — School of Physics, University of Hyderabad, Hyderabad
      Physical Sciences 2020

    • Editorial Note on Continuous Article Publication

      Posted on July 25, 2019

      Click here for Editorial Note on CAP Mode

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