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Zinc–nickel electrodeposits; aldehydes; alloy characterization; surface morphology.

Zinc alloy offers superior sacrificial protection to steel as the alloy dissolves more slowly than pure zinc. The degree of protection and the rate of dissolution depend on the alloying metal and its composition. Zinc-nickel alloy may also serve as at less toxic substitute for cadmium. In this paper the physico-chemical characterization of zinc-nickel electrodeposits obtained from sulphamate bath containing substituted aldehydes was carried out using hardness testing, X-ray diffraction, and corrosion resistance measurements. The corrosion behaviour of these samples in a 3.5% NaCl solution was examined. The decrease in 𝐼_corr and high charge transfer resistance indicated the improved corrosion resistance of these deposits.

Visalakshi Ravindran¹ V S Muralidharan¹

1. Central Electrochemical Research Institute, Karaikudi 630 006, India

Published

June 2006

Manuscript received

20 September 2005

Manuscript revised

2 January 2006