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      https://www.ias.ac.in/article/fulltext/boms/028/06/0599-0602

    • Keywords

       

      Makrofol-DE; FTIR; DSC; TGA; a.c. electrical frequency.

    • Abstract

       

      Irradiation effects of a 3 MeV proton beam on polycarbonate (makrofol-DE (MFD)) have been studied with respect to its electrical, thermal and structural behaviour by using an LCR meter, DSC/TGA and FTIR spectroscopy. The dielectric loss/constant was observed to change with the fluence. Thermal analysis revealed that chain scission is the dominant phenomena in irradiated samples based on the reduction of its thermal stability by about 19% at a fluence of 1015 ions/cm2, which is also corroborated by FTIR spectra. No significant change in intensity of the absorbance bands of the irradiated sample was observed up to a fluence of 1014 ions/cm2 while on increasing fluence (1015 ions/cm2) the polymer structure was modified. It appears from DSC thermograms that 𝑇g is observed to change with fluence.

    • Author Affiliations

       

      N L Singh1 Nilam Shah1 K P Singh2

      1. Physics Department, M.S. University of Baroda, Vadodara 390 002, India
      2. Department of Physics, Punjab University, Chandigarh 160 014, India
    • Dates

       
  • Bulletin of Materials Science | News

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