• XRD and optical microscopic studies of Co(III) complexes containing 5-cyano-6-(4-pyridyl)-2-thiouracil, thymine and adenine bases

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      https://www.ias.ac.in/article/fulltext/boms/024/03/0339-0344

    • Keywords

       

      Supramolecular; hydrogen-bonding; thymine; adenine.

    • Abstract

       

      Multifunctional ligand 5-cyano-6-(-4-pyridyl)-2-thiouracil (L) was prepared and allowed to react with trans [Co(en)2Cl2]+Cl resulting into [Co(en)2LCl]2+.2Cl which upon further reaction with equimolar ratio of ligand [L] gave the complex [Co(en)2L2]3+.3Cl. These metal complexes were then separately reacted with thymine and adenine bases. Complexes thus prepared after characterization by their elemental analysis, FAB mass and spectral (IR, 1HNMR, UV-visible) data were studied for their powder X-ray diffraction and optical microscopic characteristics.

    • Author Affiliations

       

      Lallan Mishra1 Brajesh Pathak1 R K Mandal2

      1. Department of Chemistry, Banaras Hindu University, Varanasi 221 005, India
      2. Department of Metallurgical Engineering, Banaras Hindu University, Varanasi 221 005, India
    • Dates

       
  • Bulletin of Materials Science | News

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