• Structural and magnetic properties of CaMg2Fe16O27

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/boms/024/01/0047-0050

    • Keywords

       

      W-type ferrite; electrical conductivity; paramagnetic susceptibility; Curie molar constant.

    • Abstract

       

      A new compound, CaMg2Fe16O27, is synthesized for the first time, in polycrystalline form, using stoichiometric mixture of oxides with standard ceramic technique and characterized by X-ray diffraction. It is found to have a hexagonal W-type structure with lattice parameters 𝑎 = 5.850 Å and 𝑐 = 33.156 Å. Electrical studies show that the compound is a semiconductor with energy of activation, 𝛥 𝐸 = 0.56 eV. Electrical conductivity results show a transition in the conductivity vs temperature plot near the Curie temperature. The activation energy value obtained for the paramagnetic phase is found to be higher than that of the ferrimagnetic phase. The molar magnetic susceptibility was measured in the temperature range 300–850 K and the results show that the compound is ferrimagnetic at room temperature. The compound also shows hysteresis at 300 K. Paramagnetic nature of the sample above Curie temperature is also studied. The Curie molar constant 𝐶𝑀 calculated from the plot of 1/𝜒𝑀 vs 𝑇(𝐾) is found to be nearly in agreement with the expected value.

    • Author Affiliations

       

      P S Sawadh1 D K Kulkarni2

      1. Department of Physics, B.D. College of Engineering, Wardha 442 001, India
      2. Department of Physics, Institute of Science, Nagpur 440 001, India
    • Dates

       
  • Bulletin of Materials Science | News

    • Dr Shanti Swarup Bhatnagar for Science and Technology

      Posted on October 12, 2020

      Prof. Subi Jacob George — Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bengaluru
      Chemical Sciences 2020

      Prof. Surajit Dhara — School of Physics, University of Hyderabad, Hyderabad
      Physical Sciences 2020

    • Editorial Note on Continuous Article Publication

      Posted on July 25, 2019

      Click here for Editorial Note on CAP Mode

© 2021-2022 Indian Academy of Sciences, Bengaluru.