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Oxides; X-ray diffraction; ordering; dielectric materials

Oxides of the type Ba_3-xSr_xMgNb₂O₉ were synthesized by the solid state route. Thex = 0 composition (Ba₃MgNb₂O₉) was found to crystallize in a disordered (cubic) perovskite structure when sintered at 1000C. For higher Sr doping (x ≥ 0.5), there was clearly the presence of an ordered hexagonal phase indicated by the growth of superstructure reflections in the powder X-ray diffraction patterns. In all the compositions there was the presence of a minor amount of Ba_5-xSr_xNb₄O₁₅ phase which increased with Sr substitution up tox = 1 and then it remained nearly constant at about 5%. Samples sintered at 1300C showed the hexagonally ordered phase for the entire range of composition (0 ≤x ≤ 3). The degree of ordering being considerably greater than in the 1000C heated samples as evidenced by several superstructure reflections

M Thirumal¹ A K Ganguli¹

1. Department of Chemistry, Indian Institute of Technology, New Delhi - 110 016, India

Published

December 2000

Manuscript received

5 June 2000