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    • Mixed conduction in charge transfer materials based on aromatic diamines and iodine having different mole ratios

      Ram Adhar Singh Vinod Kumar Singh

      Volume 20 Issue 3 June 1997 pp 305-315

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/boms/020/03/0305-0315

    • Keywords

       

      Charge transfer materials; mixed conduction; transport numbers; electrical conductivity

    • Abstract

       

      Mixed ionic and electronic conduction in charge transfer materials based on aromatic diamine electron donors (benzidine,o-tolidine (3,3′-dimethyl benzidine) andN,N′-diphenylbenzidine) with iodine in different mole ratios has been reported. The current-voltage and capacitance-voltage curves as a function of time and temperature have been obtained to determine the role of ionic conduction in electronic conductors based on charge transfer complexes. The compositional dependence of ionic transport numbers, diffusion parameters, ionic(σi) and electronic(σe) conductivities and thermal activation energies has been studied. Temperature and frequency dependence of AC impedance and related parameters have been studied to learn about the electrical conduction behaviour in these non-stoichiometric charge transfer materials. An electrochemical mechanism has been proposed to account for the ionic conduction in some of these complexes.

    • Author Affiliations

       

      Ram Adhar Singh1 Vinod Kumar Singh1

      1. Molecular Electronics Laboratory, Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi - 221 005, India

    • Dates

       
      Published
      June 1997
      Manuscript received
      12 June 1996
      Manuscript revised
      11 February 1997

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