• Fulltext


        Click here to view fulltext PDF

      Permanent link:

    • Keywords


      Organic semiconductors; films; polymer

    • Abstract


      The photocurrent and electrolyte electromodulation (EEM) spectra of thin films of metal-free phthalocyanine (H2Pc) and of copper phthalocyanine (CuPc) were investigated. The modulation spectra yielded three distinct features around 1·61, 2·30 and 2·93 eV for H2Pc and around 1·63, 2·04 and 3·20 eV for CuPc. The spectral dependence maxima of photoconductivity correspond to the modulation spectra. These features are interpreted to indicate transitions at critical points, i.e. the existence of transitions between three valence bands, since Pc’s are p-type, and the lowest conduction band in Pc’s.

    • Author Affiliations


      Francis P Xavier1 2 George J Goldsmith1

      1. Physics Department, Boston College, Chestnut Hill, MA - 02167, USA
      2. Physics Department, Loyola College, Madras - 600 034, India
    • Dates

  • Bulletin of Materials Science | News

    • Editorial Note on Continuous Article Publication

      Posted on July 25, 2019

      Click here for Editorial Note on CAP Mode

© 2017-2019 Indian Academy of Sciences, Bengaluru.