• Electrical and magnetic studies of iron (III) vanadate

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/boms/018/03/0229-0236

    • Keywords

       

      Conduction; stoichiometric composition; superexchange; antiferromagnetic ordering

    • Abstract

       

      Iron(III) vanadate (FeVO4) is an n-type semiconductor between 300 and 800 K. Electrical conduction in this phase occurs due to small deviation from oxygen stoichiometric composition. The mechanism of electrical transport is of a thermally activated hopping of charge carriers (electrons) on equivalent iron lattice sites. The FeVO4 obeys Curie-Weiss law between 80 and 300 K. The measured magnetic moment (μeff) of Fe3+ ion in FeVO4 is 5·270 BM at 298 K, which is lower than theμspin only value. The predominant exchange interactions are the weak 90° M-O-M superexchange and M-O-O-M super-super-exchange. The negative Weiss constantϑ=− 30 K of the phase indicated the possibility of an antiferromagnetic ordering of the iron(III) vanadate lattice. The IR absorption spectrum of FeVO4 gave bands at 990, 900, 825 and 725 cm−1 due to the presence of distorted VO4 polyhedra of the lattice.

    • Author Affiliations

       

      N Suresh Rao O G Palanna1

      1. Materials Science Research Laboratory, Department of Chemistry, St. Philomena College, Puttur - 574 202, India
    • Dates

       
  • Bulletin of Materials Science | News

    • Editorial Note on Continuous Article Publication

      Posted on July 25, 2019

      Click here for Editorial Note on CAP Mode

© 2017-2019 Indian Academy of Sciences, Bengaluru.