• Thermoelectric power of ferroelectric potassium vanadate, cesium vanadate, lithium vanadate and their solid solutions

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    • Keywords


      Thermoelectric power; phase transition; vanadate solid solutions

    • Abstract


      The thermoelectric power of the vanadates of potassium, cesium and lithium and their solid solutions was measured in the temperature range covering their transition points. The thermoelectric power measurement was carried out by the two-electrode technique for pellets of polycrystalline ceramic samples. The thermoelectric power increased with temperature initially, then decreased attaining a zero value at the transition temperature. As the concentration of KVO3 increased the thermoelectric power decreased for the solid solutions (Kx − Cs1−x)VO3, whereas the thermoelectric power increased with increase in concentration of KVO3 for the solid solutions (Kx − Li1−x)VO3. Vanadates of potassium, cesium, and lithium and their solid solutions showedP type semiconductor behaviour in ferroelectric state andn type semiconductor behaviour in paraelectric region.

    • Author Affiliations


      A J Kulkarni1 2 S P Rasal1 3 T S Magdum1 4 S H Chavan1

      1. Department of Physics, Shivaji University, Kolhapur - 416 004, India
      2. Walchand Institute of Technology, Solapur - 413 006, India
      3. Mudhoji College, Phaltan - 415 523, India
      4. Vivekanand College, Kolhapur - 416 002, India
    • Dates

  • Bulletin of Materials Science | News

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