Correlation between the magnetic properties and the chemical shifts in x-ray absorption spectra of some transition metal compounds
Studies on the chemical shifts of the K x-ray absorption discontinuities of some transition metal compounds recently conducted in our laboratory have revealed that the ΔE vs q curves do not pass through the origin. For such systems one obtains an intercept on the ΔE axis, which seems to depend uponnd, the number of unpairedd electrons. As is well-known the magnetic properties of the compounds of transition metal elements are governed by thed electrons. It is shown that the magnetic properties of the transition metal compounds may be correlated with x-ray absorption spectra.
Volume 42 | Issue 6
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