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Volume Effects in Potentiometric Titrations Chemical titration is one of the important methods in chemical
analysis. The titration can be non-instrumental or instrumental.
In the present day trend of automation, instrumental methods are
preferred. In the undergraduate and postgraduate courses important
instrumental methods employed are potentiometric and conductometric
titrations. Usually changes near the equivalence point are used
for identifying the end point and they need to be sharp for better
utility.
A Graph-theoretic
Treatment of the I like to ask my undergraduate students the following question: Consider a planet in a perfectly circular orbit around the Sun. Now take a celestial hammer and give it a slight radial knock. What happens? The answer, of course, is that the planet oscillates radially as it goes around the Sun. Radial oscillation combines with circular motion to give a plausible planetary orbit. So long as the eccentricity of the orbit is small, the radial motion is harmonic and determining the orbit is simpler than solving the general problem of planetary orbits. This approach is perhaps more insightful: it allows us to understand intuitively why a planetary orbit is closed, and why it is stable, and, with a little generalization, to determine the effect on a planetary orbit of the oblateness of the Sun and of corrections due to the general theory of relativity.
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Tel: 91-80-3612546, 3614592, 3612943 Fax: 91-80-361 6094 email: resonanc@ias.ernet.in URL: http://www.ias.ac.in |
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